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光学 2

扩散输移 2

气动光学 2

湍流 2

湍流边界层 2

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相干结构 2

空气动力学 2

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k-ε模型 1

中小企业 1

亲钠性铋基材料 1

代数应力湍流模型 1

低孔渗储层 1

体积流 1

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Experimental study of humid air reverse diffusion combustion in a turbulent flow field

GE Bing, ZANG Shusheng, GU Xin

《能源前沿（英文）》 2007年第1卷第4期页码 428-434 doi: 10.1007/s11708-007-0062-6

摘要： Experiments were performed to investigate the differences between the propane/air turbulent diffusion reactive flows past bluff-body and the propane/humid air turbulent diffusion reactive flows in the same conditions. The velocity

关键词： propane/humid propane/air turbulent bluff-body turbulent diffusion

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曲线坐标下平面二维污染物扩散输移的代数应力湍流模型

吴修广,沈永明,王敏,杨志峰

《中国工程科学》 2005年第7卷第7期页码 60-64

摘要：

对浅水流动的控制方程和深度平均的污染物扩散输移的控制方程进行坐标变换，湍流的模拟采用各向异性代数应力湍流模式，建立了曲线坐标下平面二维水流计算和污染物扩散输移的代数应力湍流模型。采用具有浓度实测值的实验室连续弯道进行模型验证，对本模型计算的浓度分布与k-ε模型进行比较，结果显示了本模型在处理各向异性明显优于k-ε模型。

关键词：污染物扩散输移各向异性代数应力湍流模型 k-ε模型

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Large eddy simulation of turbulent buffet forces in flow induced vibration

XI Zhide, CHENG Bingde, LI Pengzhou

《能源前沿（英文）》 2008年第2卷第4期页码 524-527 doi: 10.1007/s11708-008-0099-x

摘要： The pressure pulse filter and Smagorinsky sub-grid stress model of the Large Eddy Simulation (LES) are introduced. The fluid field in the annular plenum between the pressure vessel and the core barrel of the1:5 model in the second phase of Qinshan Nuclear Power Plant is simulated, and the distribution of the total pressure in the space and time domains is obtained. The results show that the Power Spectrum Density (PSD) of LES from the calculation and the test are in the same quantity order. Thus, the pressure of LES can be a load to stimulate the barrel vibration.

关键词： Spectrum Density Smagorinsky sub-grid vibration calculation Qinshan Nuclear

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Numerical simulation of three-dimensional turbulent flow in multistage axial compressor blade row

JIANG Jian, LIU Bo, WANG Yangang, NAN Xiangyi

《能源前沿（英文）》 2008年第2卷第3期页码 320-325 doi: 10.1007/s11708-008-0041-2

摘要： Numerical simulation of three-dimensional turbulent flow in a multistage axial compressor blade row is conducted. A high resolution, third-order ENN scheme is adopted to catch the shockwave and simulate the turbulent flow correctly,

关键词： simulation compressor multistage third-order three-dimensional turbulent

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URANS simulation of the turbulent flow in tight lattice bundle

Yiqi YU, Yanhua YANG

《能源前沿（英文）》 2011年第5卷第4期页码 404-411 doi: 10.1007/s11708-011-0165-7

摘要： The flow structure in tight lattice is still of great interest to nuclear industry. An accurate prediction of flow parameter in subchannels of tight lattice is likable. Unsteady Reynolds averaged Navier Stokes (URANS) is a promising approach to achieve this goal. The implementation of URANS approach will be validated by comparing computational results with the experimental data of Krauss. In this paper, the turbulent flow with different Reynolds number (5000–215000) and different pitch-to-diameter( / ) (1.005–1.2) are simulated with computational fluid dynamics (CFD) code CFX12. The effects of the Reynolds number and the bundle geometry ( / ) on wall shear stress, turbulent kinetic energy, turbulent mixing and large scale coherent structure in tight lattice are analyzed in details. It is hoped that the present work will contribute to the understanding of these important flow phenomena and facilitate the prediction and design of rod bundles.

关键词： tight rod bundle flow structure unsteady Reynolds averaged Navier Stokes (URANS)

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A comprehensive assessment on the durability of gas diffusion electrode materials in PEM fuel cell stack

Arunkumar JAYAKUMAR

《能源前沿（英文）》 2019年第13卷第2期页码 325-338 doi: 10.1007/s11708-019-0618-y

摘要： Polymer electrolyte membrane (PEM) fuel cell is the most promising among the various types of fuel cells. Though it has found its applications in numerous fields, the cost and durability are key barriers impeding the commercialization of PEM fuel cell stack. The crucial and expensive component involved in it is the gas diffusion electrode (GDE) and its degradation, which limits the performance and life of the fuel cell stack. A critical analysis and comprehensive understanding of the structural and functional properties of various materials involved in the GDE can help us to address the related durability and cost issues. This paper reviews the key GDE components, and in specific, the root causes influencing the durability. It also envisages the role of novel materials and provides a critical recommendation to improve the GDE durability.

关键词： PEM fuel cell gas diffusion electrode(GDE) gas diffusion layer(GDL) membrane electrode assembly durability fuel cell catalyst

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Numerical simulation of the characteristics of turbulent Taylor vortex flow

ZHOU Xiantao, PAN Jiazhen, CHEN Liqing, SHI Yan, CHEN Wenmei, CHU Liangyin

《化学科学与工程前沿（英文）》 2007年第1卷第2期页码 195-201 doi: 10.1007/s11705-007-0036-2

摘要： Turbulent Taylor vortex flow, which is contained between a rotating inner cylinder and a coaxial fixed outer cylinder with fixed ends, is simulated by applying the development in Reynolds stress equations mold (RSM) of the micro-perturbation. This resulted from the truncation error between the numerical solution and exact solution of the Reynolds stress equations. Based on the numerical simulation results of the turbulent Taylor vortex flow, its characteristics such as the fluctuation of the flow field, the precipitous drop of azimuthal velocity, the jet flow of radial velocity, the periodicity of axial velocity, the wave periodicity of pressure distribution, the polarization of shear stress on the walls, and the turbulence intensity in the jet region, are discussed. Comparing the pilot results measured by previous methods, the relative error of the characteristics predicted by simulation is less than 30%.

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Safety and serviceability assessment for high-rise tower crane to turbulent winds

Zhi SUN, Nin HOU, Haifan XIANG

《结构与土木工程前沿（英文）》 2009年第3卷第1期页码 18-24 doi: 10.1007/s11709-009-0009-2

摘要： Tower cranes are commonly used facilities for the construction of high-rise structures. To ensure their workability, it is very important to analyze their response and evaluate their condition under extreme conditions. This paper proposes a general scheme for safety and serviceability assessment of high-rise tower crane to turbulent winds based on time domain buffeting response analysis. Spatially correlated wind velocity field at the location of the tower crane was first simulated using an algorithm for generating the time domain samples of a stationary, multivariate stochastic process according to some prescribed spectral density matrix. The buffeting forces applied to the structure were computed according to the above-simulated wind velocity fluctuations and the lift, drag, and moment coefficients obtained from a CFD computation. Those spatially correlated loads were then fed into a well calibrated finite element model and the nonlinear time history analysis was conducted to compute structural buffeting response. Compared with structural on-site response measurement, the computed response using the proposed method has good precision. The proposed method is then adopted for analyzing the buffeting response of an in-use tower crane under the design wind speed and the maximum operational wind speed for safety and serviceability assessment.

关键词： tower crane buffeting response wind velocity modeling

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Coupled diffusion of chloride and other ions in saturated concrete

Nattapong DAMRONGWIRIYANUPAP, Linyuan LI, Yunping XI

《结构与土木工程前沿（英文）》 2011年第5卷第3期页码 267-277 doi: 10.1007/s11709-011-0112-z

摘要： Corrosion of reinforcing steel due to chloride ions is one of the severe deterioration problems in long-term performance of reinforced concrete structures. The deterioration process is frequently found in marine concrete structures, highway pavements, and bridges exposed to deicing salts. The diffusion of chloride ions is associated and strongly affected by other ions in the pore solution in concrete. In this paper, chloride penetration into concrete structures was mathematically characterized by the Nernst-Planck equation which considered not only diffusion mechanism of the chloride ions but also ionic interaction among other ions coming from externally applied deicers and within the Portland cement paste. Electroneutrality was used to determine the electrostatic potential induced by the ionic interaction. The material models of chloride binding capacity and chloride diffusion coefficient were incorporated in the governing equations. The governing equations were solved by using finite element method. A numerical example was used to illustrate the coupling effect of multi-ionic interactions and the effect of influential parameters. The numerical results obtained from the present model agreed very well with available test data.

关键词： diffusion chloride concrete Nernst-Planck equation durability

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Preparation of a Pb loaded gas diffusion electrode and its application to CO

Ang LI, Hua WANG, Jinyu HAN, Li LIU

《化学科学与工程前沿（英文）》 2012年第6卷第4期页码 381-388 doi: 10.1007/s11705-012-1216-2

摘要： A Pb loaded gas diffusion electrode was fabricated and used for the electroreduction of CO to formic acid. The Pb/C catalyst was prepared by isometric impregnation. The crystal structure and morphology of the Pb/C catalyst were characterized by X-ray diffraction (XRD) and transmission electron microscope (TEM). The preparation conditions of the gas diffusion electrode were optimized by adjusting the amounts of polytetrafluoroethylene (PTFE) in the gas diffusion layer and acetylene black in the catalytic layer. The electrochemical performance of the as-prepared gas diffusion electrode was studied by chronoamperometry and cyclic voltammetry. The optimized gas diffusion electrode showed good catalytic performance for the electroreduction of CO . The current efficiency of formic acid after 1 h of operation reached a maximum of 22% at -2.0 V versus saturated calomel electrode (SCE).

关键词： electroreduction carbon dioxide lead catalyst gas diffusion electrode formic acid

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evaluation of renal function using diffusion weighted imaging and diffusion tensor imaging in type 2

null

《医学前沿（英文）》 2014年第8卷第4期页码 471-476 doi: 10.1007/s11684-014-0365-8

摘要：

This work aims to estimate the value of diffusion weighted imaging (DWI) and diffusion tensor imaging (DTI) in detecting early-stage kidney injury in type 2 diabetic patients with normoalbuminuria (NAU) versus microalbuminuria (MAU) prospectively. A total of 30 T2DM patients with normal kidney function were recruited and assigned to the NAU group (n = 14) or MAU group (n= 16) according to 8 h overnight urinary albuminuria excretion rate (AER) results. A contemporary cohort of health check-up recipients were included as controls (n = 12). DWI and DTI scans were performed on bilateral kidney using SE single-shot EPI, and apparent diffusion coefficient (ADC) and fractional anisotropy (FA) of the renal parenchyma was determined from ADC and FA maps of the three groups. ADC and FA values were compared among the three groups. According to DWI with a b value of 400 s/mm², the MAU and NAU groups showed significantly lowered mean ADC values compared with the healthy controls (P<0.01). The mean ADC in the MAU group [(2.22±0.07)×10^–3 mm²/s] was slightly lower than that of the NAU group [(2.31±0.22)×10^–3 mm²/s], but this difference was not statistically significant (P>0.05). The FA value in the MAU group was higher than that in the control group (0.45±0.07 vs. 0.39±0.03, P = 0.004) but did not differ from that in the NAU group (0.42±0.03) (P>0.05). ADC and FA values may be more sensitive than urine AER in reflecting early-stage kidney injury and, hence, may facilitate earlier detection and quantitative evaluation of kidney injury in T2DM patients. Combined evaluation of ADC and FA values may provide a better quantitative approach for identifying diabetic nephropathy at early disease stages.

关键词： type 2 diabetes mellitus microalbuminuria diffusion weighted imaging diffusion tensor imaging early-stage kidney injury

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Magnetohydrodynamic slip flow and diffusion of a reactive solute past a permeable flat plate with suction

Krishnendu BHATTACHARYYA, G. C. LAYEK

《化学科学与工程前沿（英文）》 2011年第5卷第4期页码 471-476 doi: 10.1007/s11705-011-1130-z

摘要： The magnetohydrodynamic (MHD) boundary layer slip flow and solute transfer over a porous plate in the presence of a chemical reaction are investigated. The governing equations were transformed into self-similar ordinary differential equations by adopting the similarity transformation technique. Then the numerical solutions are obtained by a shooting technique using the fourth order Runge-Kutta method. The study reveals that due to the increase in the boundary slip, the concentration decreases and the velocity increases. On the other hand, with an increase in the magnetic field and mass suction, both boundary layer thicknesses decreased. As the Schmidt number and the reaction rate parameter increases, the concentration decreases and the mass transfer increases.

关键词： slip flow MHD boundary layer reactive solute diffusion flat plate suction/injection

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Molecular diffusion in ternary poly(vinyl alcohol) solutions

《化学科学与工程前沿（英文）》 2022年第16卷第6期页码 1003-1016 doi: 10.1007/s11705-021-2121-3

摘要： The diffusion kinetics of a molecular probe—rhodamine B—in ternary aqueous solutions containing poly(vinyl alcohol), glycerol, and surfactants was investigated using fluorescence correlation spectroscopy and dynamic light scattering. We show that the diffusion characteristics of rhodamine B in such complex systems is determined by a synergistic effect of molecular crowding and intermolecular interactions between chemical species. The presence of glycerol has no noticeable impact on rhodamine B diffusion at low concentration, but significantly slows down the diffusion of rhodamine B above 3.9% (w/v) due to a dominating steric inhibition effect. Furthermore, introducing surfactants (cationic/nonionic/anionic) to the system results in a decreased diffusion coefficient of the molecular probe. In solutions containing nonionic surfactant, this can be explained by an increased crowding effect. For ternary poly(vinyl alcohol) solutions containing cationic or anionic surfactant, surfactant–polymer and surfactant–rhodamine B interactions alongside the crowding effect of the molecules slow down the overall diffusivity of rhodamine B. The results advance our insight of molecular migration in a broad range of industrial complex formulations that incorporate multiple compounds, and highlight the importance of selecting the appropriate additives and surfactants in formulated products.

关键词： fluorescence correlation spectroscopy poly(vinyl alcohol) anomalous diffusion crowding effects dynamic light scattering binding effects rhodamine B

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Reaction kinetics and internal diffusion of Zhundong char gasification with CO

Yun Liu, Jiangyuan Qu, Xuehui Wu, Kai Zhang, Yuan Zhang

《化学科学与工程前沿（英文）》 2021年第15卷第2期页码 373-383 doi: 10.1007/s11705-020-1949-2

摘要： Mass transfer usually affects the rate of chemical reactions in coal. The effect of internal diffusion on char gasification with CO in the temperature range from 1123 K to 1273 K was investigated via thermo-gravimetric analysis and assessment of char morphology features. The results revealed that the effect of internal diffusion on the initial reaction rate was more significant with an increase of particle size, due to the concentration gradient of the gasification agent within the solid particles. In the early stage of gasification, the generation of new micropores and the opening of closed pores led to an increase in specific surface area. As the reaction proceeded, the openings were gradually expanded and the specific surface area continued to increase. However, with further reaction, disappearance of edge pores, melting and collapse of the pore structure led to a decrease in specific surface area. The intrinsic activation energy and reaction order based on the th-order model were 157.67 kJ∙mol and 0.36, respectively. Thus, temperature zones corresponding to chemical reaction and diffusion control were identified. Moreover, the calculated effectiveness factor provided a quantitative estimation of internal diffusion in the initial stage.

关键词： coal char CO₂ gasification internal diffusion pore evolution

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Chloride diffusion in concrete with carbonated recycled coarse aggregates under biaxial compression

《结构与土木工程前沿（英文）》 2023年第17卷第4期页码 637-648 doi: 10.1007/s11709-023-0902-0

摘要： Chloride attack on concrete structures is affected by the complex stress state inside concrete, and the effect of recycled aggregates renders this process more complex. Enhancing the chloride resistance of recycled concrete in a complex environment via carbonization facilitates the popularization and application of recycled concrete and alleviates the greenhouse effect. In this study, the chloride ion diffusion and deformation properties of recycled concrete after carbonization are investigated using a chloride salt load-coupling device. The results obtained demonstrate that the chloride ion diffusivity of recycled concrete first decreases and then increases as the compressive load increases, which is consistent with the behavior of concrete, in that it first undergoes compressive deformation, followed by crack propagation. Carbonation enhances the performance of the recycled aggregates and reduces their porosity, thereby reducing the chloride diffusion coefficient of the recycled concrete under different compressive load combinations. The variation in the chloride ion diffusivity of the carbonized recycled aggregate concrete with the load is consistent with a theoretical formula.

关键词： recycled concrete carbonated recycled coarse aggregate biaxial compression chloride diffusion stress level